Folk School

Browns and Grays: Walnut, Butternut, Bark, and Iron

The nut trees and oaks of an Eastern or Midwestern woodlot make the most dependable natural browns. Black walnut hulls dye wool dark brown with no mordant at all; butternut hulls with alum give a fast brown that an iron afterbath darkens toward black; oak and other barks give tans and browns. Plus the lichens Scandinavian dyers used.

  • 5 min
  • 5 steps
  • 3 questions
  • Lesson 109 of 204

In this lesson

  1. Black walnut
  2. Butternut
  3. Oak and other barks
  4. Lichens
  5. Try it

Many of the most dependable natural browns come from trees: walnut, butternut, hickory, and oak 1.

Black walnut

Both the hulls and the shells of the black walnut (Juglans nigra) are used. Collect the hulls while they’re green, then use them fresh or dry them. Many dyers think dried hulls make better dye. Another old method is to cover the green hulls with water and store them away from the light, where the color grows darker and seems to improve on standing 1.

Four black walnuts lying in grass and fallen leaves, their husks blackened and wrinkled, one split open to show the dark nut inside.
Fallen black walnuts. The husks, or hulls, hold the dye. Credit: Virginia State Parks staff · CC BY 2.0 · Source

Walnut is the easiest natural dye there is, because it’s substantive: it needs no mordant 2. On unmordanted wool, black walnut hulls give a dark brown with good fastness. With alum the color is a bit brighter but only fair to light 1.

Dark brown, for 1 pound of unmordanted wool 1:

  1. Soak ½ peck of green black walnut hulls in water to cover for 30 minutes, then boil 15 minutes.
  2. Strain, and add cold water to make 4 to 4½ gallons.
  3. Put in the wet wool and boil 20 minutes. Rinse and dry.

Don’t boil wool long in walnut dye; it makes the wool harsh 1. Wear the rubber gloves the USDA recommends for all dyeing 1; walnut stains hands brown. On alum-mordanted cotton, walnut gives a drab with good fastness to light, and an iron afterbath makes it darker 1.

Quick check

Why don’t black walnut hulls need a mordant on wool?

Butternut

Butternut (Juglans cinerea), grows in the woods of the Eastern and Central states. Its bark, roots, leaves, and hulls all make dye. Gather the nuts green and let them ripen partly; then the hulls are ready to use, or dry them for later 1.

On alum-mordanted wool, butternut hulls give a fast brown, fair to light. Add iron and it darkens, even to black, depending on how much you use 1.

Brown, for 1 pound of alum-mordanted wool 1:

  1. Soak 1 peck of green butternut hulls in water to cover for 30 minutes, then boil 15 to 30 minutes.
  2. Strain, and add cold water to make 4 to 4½ gallons.
  3. Put in the wet wool and boil 30 minutes. Rinse and dry.

For a darker brown, move the dyed wool, without rinsing, into a boiling bath of about 1/6 ounce of ferrous sulfate (copperas) in 4 to 4½ gallons of water, and boil 10 minutes more. Rinse and dry 1. Iron saddens every color it touches; too much hardens wool and makes it streak 2.

Quick check

What does an iron (copperas) afterbath do to butternut brown?

Oak and other barks

The barks of many common trees give tans and browns on wool; on cotton, only the lighter shades. Of the barks the USDA tested, black oak (quercitron) had the most coloring power. Collect most barks in fall or winter. The inner bark is generally used, fresh or dried, and fresh usually gives a stronger dye. Dry bark carefully and store it where it won’t mold 1.

The basic bark method, for 1 pound of wool, unmordanted or mordanted with alum 1:

  1. Soak 1 peck of finely chopped bark overnight in 2 to 2½ gallons of soft water.
  2. In the morning heat slowly and boil 2 hours, adding hot water as it boils away.
  3. Strain twice through cheesecloth, and add cold water to make 4 to 4½ gallons.
  4. Let it cool to lukewarm, put in the wet wool, and boil 30 minutes. Rinse and dry.

One caution: bark color is closely combined with tannin, so bark-dyed fabric often isn’t fast to light and soon darkens toward brown 1. The bulletin’s other bark methods fix that with chrome, copper, or iron afterbaths; of those, only the iron one (1/6 ounce of ferrous sulfate, boiled 10 minutes) belongs in a home dye kitchen today 1 2.

Walnut Dye: Early American Fabric Walnut dye as early Americans made it. Credit: Townsends · YouTube standard license · 11:33 · Source

Playback is optional. If the player is unavailable, open the video at its source.

Quick check

Why do bark-dyed browns often darken in the light?

Lichens

The USDA noted that the peasant dyers of Sweden, Scotland, and Ireland colored woolens brown, yellow, red, and purple with lichens. The bulletin recommended collecting them in August, and passed on the saying that lichens growing on stone give better color than the same kinds on trees 1. Some lichens are substantive dyes like walnut 2. The leafy, flat Peltigera, boiled for an hour from a peck of crushed dry lichens and used on alum-mordanted wool, gave the USDA a yellow-tan, fair to light and good to washing 1.

Try it

In the fall, gather a bucket of fallen black walnuts, peel off the green or blackening hulls (with gloves on), and dye one skein of unmordanted wool and one mordanted with alum in the same bath. Compare them, and put both in the light test.

Lesson complete

Nice work.

1day streak
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Reds: Madder and Cochineal

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Sources for this lesson
  1. 1
    Margaret S. Furry, Bess M. Viemont. Home Dyeing with Natural Dyes (Miscellaneous Publication No. 230). U.S. Department of Agriculture, Bureau of Home Economics. 1935. verifiedTests of about 65 natural dye materials on cotton and wool; only colors fast to light and washing were given recipes. Wool dyes most easily; cotton only by complicated processes. Home light test: dyed cloth between two cards with matching 2-inch windows, outdoors tilted toward the sun a few days. Home wash test: 2 by 4 inch dyed piece sewn to undyed cloth. Equipment: scales, enamel or copper kettles (iron darkens, tin makes colors harsh), measures, cheesecloth, smooth sticks, thermometer, rubber gloves, line in the shade, soft water. Weigh dry first. Wool scour: 3/4 oz neutral soap per pound in 5 gal at 95 F, 30 min, again with 1/4 the soap, rinse 3 or 4 times at the same temperature; never wring; sudden temperature changes shrink wool. Mordants: alum, chrome (potassium dichromate), copperas, tannin. Wool alum mordant: 4 oz potash alum and 1 oz cream of tartar per pound in 4 to 4 1/2 gal, heat gradually, boil gently 1 hour, cool overnight. Cotton: alum with washing soda, or alum-tannin-alum. Dye baths: at least 4 to 4 1/2 gal per pound or streaks; wool in lukewarm, heat gradually, keep moving; rinse until clear (crocking from poor rinsing); dry in shade; dye all of a color at once because natural colors can't be matched. Not fast: annatto, barberry root, beets, crab-apple peel, blackberry, blueberry, cranberry, pokeweed, purple iris, mosses, peach leaves, red roses, sumac leaves, turmeric, willow leaves. Bark colors combined with tannin often darken in light. Butternut hulls (alum) fast brown, iron darkens to black. Cochineal from an insect of Mexico and Central America; alum, 1 oz per pound, American beauty red; not for cotton. Goldenrod flowers picked coming into bloom: with alum, greenish yellow not fast to light; with indigo dark greens; with madder terra cotta. Indigo needs no mordant; vat dye reduced and dissolved in alkali; greenish yellow in the vat, blue in air; fermentation blue-pot (8 oz indigo, 4 oz bran, 4 oz madder, 1 1/2 lb washing soda, 4 gal, 85 F, 5 to 10 days) and hydrosulphite vat. Madder: Egyptians, Moors, Netherlands; replaced by synthetic alizarin; 8 oz per pound with alum, lacquer red, very fast; dark red at 140-160 F without boiling. Onion skins 10 oz dry, alum: burnt orange, fair. Black walnut hulls on unmordanted wool: dark brown, good; long boiling makes wool harsh. Lichens used by peasant dyers of Sweden, Scotland, and Ireland. Top-dyeing: clear colors make clear colors; goldenrod plus indigo green; indigo plus walnut black or gray; goldenrod plus madder terra cotta.
  2. 2
    The Mordant Riff. Earth Guild (Asheville, North Carolina). 1998. verifiedSubstantive dyes (lichens, walnut hulls) need no mordant; adjective dyes do: the mordant enters deeply into the fiber and the dye combines with it. Wool is easiest. Non-reactive pot, unchipped enamel or stainless; brass, copper, or iron pots mordant on their own. Soak wool several hours; never put dry fiber in a mordant or dye pot. Simmer an hour, do not boil; heat and agitation cause felting; cool overnight. Mordanted wool can be stored wet or dry. Never use the same pots for cooking and dyeing; don't breathe fumes. Alum with cream of tartar: 3 oz alum and 1 oz cream of tartar per pound, 4 for heavy wool; too much makes wool sticky. Iron saddens; tin blooms but is caustic and makes wool brittle; blue vitriol is poisonous. Test colorfastness; fading happens with berries and some flowers.